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The Decomposition of Vanillin

Vanillin is of interest to us because it is found in the lignin component of newly harvested flax fibers. Over time, a very long time, vanillin decomposes and disappears from the fibers. For instance, if you leave a piece of linen lying around—that hasn’t had all its lignin removed by modern bleaching—for about 650 years and you then examine it for vanillin, you will find that nearly two-thirds of the vanillin has disappeared. Leave it around for another 650 years and it is all gone, or nearly so. Temperature affects the process but not drastically within the range of normal ambient temperatures. In other words, under normal conditions, it takes at least 1300 years for all of the vanillin to disappear. Raymond Rogers noticed that . . .

A linen produced in A.D. 1260 [the earliest possible date that the cloth could have been produced according to the 1988 carbon dating] would have retained about 37% of its vanillin in 1978. . . . all other medieval linens gave the test for vanillin wherever lignin could be observed on growth nodes. The disappearance of all traces of vanillin from the lignin in the shroud indicates a much older age than the radiocarbon laboratories reported. (37)

 

 

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Testing History
Have We Missed Something?
Max Frei thought so.
Pollen Identification
Scanning Electron Microscope
Attacking Frei
Der Stern
Avinoam Danin and Uri Baruch
Baruch was Guarded
Threshold For Perceiving Images
The Situationist
Pareidolia
The Face on Mars
Things People See on the Shroud
Photons by the Millions
Dirty, Creased and Wrinkled
So does the banding patterns, the variegated appearance of
Photography is Part of the Problem
Fluffy Shaped Sponge?
The Lepton
Francis Filas
Points of Congruence
Barrie Schwortz on the Coins
Limestone Dust
Textile Analysis
Stitching
Variegation
The Making of Linen
Ancient Bleaching
Bleaching in the Middle Ages
It has been noticed that the Shroud of Turin—except
The Decomposition of Vanillin
Vanillin as a Validation of Carbon Dating
Making Sense of History in Context